Dpmt Second Semester Engineering Chemistry Question Bank Solution

                  CENTRAL  INSTITUTE  OF PLASTICS ENGINEERING & TECHNOLOGY                        

                                                    Question Bank

1 MARK—QUESTION

2 MARK ---QUESTION

3 MARK --- QUESTION

4/5 MARK ----QUESTION

COURSE      : DPMT

SEMESTER: II

SUBJECT    : Engineering Chemistry

1 MARK—QUESTION(MCQ)

                                                              -------

1.     Modern Periodic table is based on ……………….

Answer:atomic number

 

2.   The idea of stationary orbits was first given by

a)Rutherfordb)J.J.Thomsonc)Niels Bohr       d) Max Plank

Answer: c) Niels Bohr  

 

3.   If A the number of nucleons and Z is the number of neutrons and, then the number of protons in an atom is givenby……………………

               a) A+Z b)A-Z                 c)Z-A               d) none ofthese

Answer: b) A-Z

 

4.   What does ‘AM’ stands for?

Answer:Atomic Mass

 

5.   Electronic configuration of N (7) is………………

Answer:1S22S22P3

 

6.   The maximum number of electrons that can be accommodated in an orbitis…………………..

a)2n b) n2c) 2n2d) 2n+1

Answer: c) 2n2

 

7.   The mass number and atomic number of sulphur atom are 32 and 16 respectively. Thenumber of neutrons in the nucleus is……………….

Answer: 16

 

8.   The particle with neutral charge in the nucleus is………..

            a)proton  b)electron c) neutron d)nucleus

Answer: c)neutron

 

9.   Bohr’s model can successfully explain the structure of hydrogen containing……….electron.

a)     1       b) 2        c) 3      d) 4

Answer: a) 1

 

10.  What does “VBT” stands for?

Answer: Valance Bond Theory

 

11.  MOT stands for……..?

Answer:Molecular orbital theory

 

12.  d- Block elements are also called ………. Metals.

a)     alkali    b) alkaline   c)transition    d)alkaline earth

Answer:c) transition

 

13.  f- Block elements are also called ………. Metals.

a)     alkali    b) inner transition   c)transition    d)alkaline earth

Answer:b) inner transition

 

14.  …….have same atomic number but different mass number.

Answer:Isotopes

 

15.  Accordingto……….itisimpossibletodeterminesimultaneouslythe position and velocity with accuracy of a small particle like electron.

a)Heisenberg’suncertaintyprinciple       b) Bohr’s atomic model      

c) Pauli’s exclusion principle d)Aufbau Rule

Answer:a) Heisenberg’suncertaintyprinciple

 

16.  Out of the following pairs of elements which has the same number of electrons in the outermostenergy level…………………….

a) heliumand lithium   b) boronandcarbon c) carbon and nitrogen d) lithium andhydrogen

Answer: d) lithium and hydrogen

 

17.  The maximum number of electrons that can be accommodated in d-subshellis………………

Answer: 10

 

18.  Isobars have same atomic number but different mass number (Say True orFalse)

Answer: False

 

19.  The most electronegative element in the periodic tableis…………………..

Answer: Fluorine

 

20.  ………………..is an electronic configuration of chromium(Cr-atomic number24).

a)1s22s22p63s23p64s23d4


b)1s22s22p63s23p64s13d5


c)1s22s22p63s23p54s23d5


d)1s22s22p63s23p54s23d4


Answer: b)1s22s22p63s23p64s13d5

 

21.  Which one of the following is the most polar …......

a)H-F      b)H-Cl               c)H-Br               d)H-I

Answer: a) H-F

 

22.  Covalent or non-polar bond is formed by …………..of electron.

a) Accepting b) donating   c) mutual sharing d) none of these

Answer:  c) mutual sharing 

 

23.  In a N2 molecule there are one sigma and two pi bonds (Say True orFalse)

Answer: True

 

24.. .................... is formed by sidewise overlapping of atomicorbitals.

Answer: Pi bond

 

25.  The high boiling point of alcohol is due to………………….

a)Covalent bonding b)Ionicbonding          c)Hydrogenbonding       d) Coordinatebonding

Answer: c) Hydrogen bonding

 

26.  An ionic bond is formed between.

a) Two metals atoms                                        b) Two non-metals atoms

c) One metal atom and one non-metal atom    d) One metal atom and and one non-metalloid atom            

Answer: c) One metal atom and one non-metal atom

 

27.  In a chemical bonding the atom attains …………configuration.

a) Partially filled    b) half-filled c) vacant d) octet or inert gas

Answer:d) octet or inert gas

 

28.  Bonding between a metal ion and a ligand is known as …………bond.

a)Covalent bonding b)Ionicbonding          c)Hydrogenbonding       d) Coordinatebonding

Answer: d) Coordinate bonding

 

29.  ……… & …………. are the two types of hydrogen bonding.

a)Inter and intramolecularb)Ionic and covalent    c) ionic and coordinate   d) None of the above

Answer: a)) Inter and Intramolecular

 

30.  Hydrogen bond is strongest in …………..

a) O-H…H       b)F-H…F  c)O-H…O      d) O-H…F

Answer: b)F-H…F

 

31.  According to Lowry-Bronsted concept, an acid is a substancethat…………………..

a) acceptsa proton

b)releasesaproton    

c) acceptsaelectron      

d) releases aelectron

Answer: a) accepts a proton

 

32.  Lewis base is a substance that accepts ………

Answer:lone pair of electron

 

33.  Molecules or ions that can behave both as Bronsted acid and base arecalled……………….

a)Monoprotic acids  

b)polyprotic Acid

c)amphiproticsubstances          

d) polyproticbases

Answer: c) amphiprotic substances

 

34.  Nitric acid is a strong acid because ithas………………………

a) highmolecularmass

b)highlyunstable             

c)high ionization           

d) lowionization

Answer: c) high ionization

 

35.  A weak base has ………..conjugate acid and a weak acid has a ………..conjugate base.

Answer:strong, strong

 

36.  Solution is a heterogeneous mixture of solute and solvent (Say True orFalse)

Answer: false

 

37.  The ionic product of water is……………………

Answer: 1 x 10-14

 

38.  ………..of a solution is the number of equivalents of solute per liter of the solution.

Answer: Normality

 

39.. Molarity of a solution is the number of gram moles of solute per liter of thesolution.(Say True orFalse)

Answer: True

 

40.  In a …………., the amount of solute is more in comparison to saturatedsolution.

a) Saturated solution  

b)unsaturated solution   

c)super saturated solution  

d) all of these

Answer: c) super saturated solution

 

41.  Solution of pH = 9 is ________.   

a)  Acidic   b) Buffer c) Neutral d) None of these

Answer: d) None of these

 

42.  For the preparation of 1000 ml of 0.1 N solution of sulphuric acid, the amount of H2SO4 needed is……………

a)4.9 g    b)9.8 g             c) 14.7g            d) 19.6 g

Answer: a) 4.9 g

 

43.  For the preparation of 1000 ml of 1 M solution of sodium carbonate, the amount of Na2CO3 needed is……………

a)53 g     b)106 g            c) 10.6g            d) 5.3 g

Answer: b) 106 g

 

44.  Polar compounds are soluble in ………..solvents.

Answer:polar

 

45.  Non-Polar compounds are soluble in non-polar solvents (Say True orFalse)

Answer: True

 

46.  pH<7, is generally calledas…………………….

Answer: acid

 

47.  The taste of an acidis………………..

Answer: Sour taste

 

48.. Blue litmus Paper turns ………..colour, ifitis acidic solution.

Answer: Red

 

49.. Red litmus paper turns blue colour, ifitis............. solution.

Answer: Alkaline

 

50.  The Major quantity of the solution is called as solvent. (Say True orFalse)

Answer: True

 

51.  Buffer solution is used to………………………

a) Increasethe pH   

b) keep the pH remains same   

c) decreasethe pH        

d) None of these

Answer: b) Keep the pH remains same

 

52.  Buffer solution is a mixture of weak acid and its…………

Answer: conjugate base

 

53.  Mixture of NH4OH and NH4Cl solution is a…………buffer.

a) basic

b) acidic

c) neutral 

d) salt

Answer: a) basic

 

54.  pH + pOH =………

a)     7  b) 14  c) 10 d) 12

Answer: b) 14

 

 

55.  Sigma Bond is weaker than pi bond .(Say True orFalse)

Answer: False

 

56.  ……….. Water produces lather with soap solution.

a)  Hard   b) soft  c) hot d) none of the above

Answer: b) soft

 

57.  Temporary hardness of water can also be called as ………….

a)     Carbonate 

b) non carbonate 

c) alkaline 

d) total

Answer: a) carbonate

 

58.  ……………of Ca andMgcreate temporaryhardness of water.

a) Carbonates     

b) Bicarbonates            

c) Carbonates and Bicarbonates

d) None of these

Answer: c) Carbonates and Bicarbonates

 

59.  Hard water can be used for washing purposes (Say True orFalse)

Answer:False

 

60.  Temporary Hardness of water can be removed by ………. the water.

Answer:Boiling

 

61.  Full form of ppb…..?

Answer: Parts per billion

 

62.. Magnesiumsulphate& chloridescreates........ hardness inwater.

a)Carbonate 

b) Total 

c) Temporary 

d) Permanent

Answer: d) permanent

 

63.  ………….waterhasH+andOH-ions.

a)Deionized

b)ionized         

c) mineral                    

d) impure

Answer: a) Deionized

 

64.  The degree of hardness of water is usually expressedas………………

Answer: parts per million(ppm)

 

65.  pH stands for…………..

Answer: Power of Hydrogen

 

66.  Full form of ppm……..

Answer: parts per million

 

67.  Calgon, Na2[Na4(PO3)6] is used as a………………………

a)water purifier    

b)water hardener  

c)watersoftener             

d) none ofthese

Answer: c) water softener

 

68.. Soap is the ………….. of higher fattyacid.

Answer:sodium salt

 

69.  Use of hard water in boilers causes……………

a)Boiler corrosion b) scales &sludges c) caustic embrittlement d) all the above

Answer: d) All the above

 

70.  The general formula of cationexchange resins is…………

a)RH+        

b) ROH-         

c)  RH2O  

d)  All the above

Answer: a) RH+

 

71.  Anion exchange resinscan be regenerated using……….

a) DiluteNaOH           b) HCl                 c) KMnO4        d) NH3

Answer: a)Dilute NaOH

 

 

72.  Permanent hardness can be removedby………………………

a) Limesoda process 

b)Permutit process   

c)Ion-exchangeprocess            

d) All of these

Answer: d) All of these

 

73.  .Ground water contains appreciable amount of calcium and magnesium salts(Say True orFalse)

Answer: True

 

74.  Full form of EDTA is……..

Answer: Ethylene diamine tetra acetic acid.

 

75.  Full form of EBT is……..

Answer:Eriochrome Black T

 

76.  Hardness of water is due to the presence of salts of……….

a)Potassium     b)chlorine        c)Magnesium      d)boron

Answer:c)Magnesium

 

77.  The functional group of acidis……………….

a)RCOOH      b)RCOOR   c)RCHO            d)RCOR

Answer :a)RCOOH

 

78.  Ester has pleasant fruity smell. (say true or false)

Answer: True

 

79.  Which one of following represents ketone group.    

(a) R-COOH   (b) R-CO-R  (c) R-OH    (d) R-COOR

Answer: (b) R-CO-R

 

80.  Acid derivatives are…….

(a) Ester   (b) Amide   (c) Anhydride   (d) All of these

Answer: (d) All of these

 

81.  What does “TAN” stands for?

Answer: (d) Total acidity Number

 

82.  Catenation is the property of carbon atom - Saytrue or false.

Answer: True

 

83.  What does “VC” stands for?

Answer: Vinyl Chloride

 

84.  Alkyl groups has one hydrogen shortage of Alkane compounds (Say True orFalse)

Answer: True

 

85.  Catenation property of carbon is responsible for the large number of carbon compounds due to its.

a)small size          b)tetrahedral structure    c)moderate electronegativity   d)All of these

Answer: d)All of these

 

86.  All Organic compounds mainly consist of…………………..

Answer: Carbon and Hydrogen

 

87.  Cyclic Compounds Contain one atom(Sulphur, Oxygen, Nitrogen) other than carbonis called………………………………

Answer: Heterocyclic Compounds

 

88.  The general formula for alkaneis………………………….

a)CnH2n+2                      

b)CnH2n           

c)CnH2n-2       

d)CnH2n+4

Answer: a) CnH2n+2

 

89.  The first synthesized organic compound from an ammonium cyanate is…………..

Answer: Urea

 

90.  The general formula for alkeneis………………………….

a)CnH2n+2                      

b)CnH2n           

c)CnH2n-2       

d)CnH2n+4

Answer: b) CnH2n

 

91.  The general formula for alkyneis………………………….

a)CnH2n+2                      b)CnH2n           c)CnH2n-2       d)CnH2n+4

Answer: c) CnH2n-2

 

92.  Methane is a major constituent of …………..

Answer :natural gas

 

93.  74. LPG ismixed with           to detect leakage.

a)hydrogen       b)oxygen          c)mercaptans    d)nitrogen

Answer: c) mercaptans

 

94.  The antiknock property of the fuel depends onits

a)Self-ignitiontemperature          

b) Molecularstructure

c)Chemicalcomposition   

d) All of theabove

Answer: d) All of the above

 

95. Decomposition of higher hydrocarbon molecules into lower hydrocarbons having lower

boiling temperatures is known as Hydrogenation (say true or false)

Answer: false

 

96.  The heat energy released is measured with the help of …………

Answer: Calorimeter

 

97.. Bomb calorimeter is used to determine the calorific value of the…............ fuels

a)Solid fuels           

b) Liquid fuels    

c) both a& b           

d) None of the abov

Answer: c) both a & b

 

98.. KJ/mol is the unit of………….

a)Calorific value     b)Work      c)Specific Heat   d)Thermal conductivity

Answer:a) Calorific value

 

99.  Coal is a …………..fuel, whereas coke is a ……….fuel.

Answer: primary& secondary

 

100.Full form of LPG………

Answer:Liquified Petroleum Gas.

 

101.Full form of TEL………

Answer: Tetra Ethyl Lead

 

102.Octane number of isooctane is ……………

a) 50     b) 1       c) 100     d) 5

Answer: c) 100

 

103.Knocking ……..  the efficiency of petrol engine.

a) increases    b) decreases      c) will not affect     d) none of these

Answer:b) decreases

 

104.Diesel can be obtained by the fractional distillation of ………….

Answer: crude oil

 

105.A mixture of ……………..is known as water gas.

Answer: carbon monoxide and hydrogen

 

106.Coke is a secondary solid fuel. (Say true or false)

Answer: True

 

107.The liquefied petroleum gas (LPG) marketed by Indian oil corporation is called………………..

Answer:Indane

 

108.A petroleum fraction obtained between 180-2500Cis……………..

a) Petrol    b) diesel       c) Kerosene     d) none of these

Answer: c) Kerosene

 

109.The fermentation process of cattle dung in the absence of air produces……….

Answer: Gobar gas

 

110.The combustion rate of solid fuels is slow because of the difficulty of thorough contact betweenthe solid fuel and oxygen. (Say True or False)

Answer: True

 

111.Burning of coal and dieselreleases………………….

a)NO2     b)CO2               c) SO2               d)CO

Answer: c) SO2

 

112.The antiknock property of gasoline can be increased by adding……….

Answer: TEL

 

113.Flow of electrons across the electrodes is known as …………

Answer: Electric Current

 

114.The conductance of a solution of an electrolyte generally increases with rise in temperature(Say True or False)

Answer: True

 

115.The units of specific conductanceare………………….

Answer: ohm-1cm-1

 

116.The conductivity of an electrolyte is due tothe………………………..

a) presence of ions intheelectrolyte    

b) free movement of ions in thesolution

c) reunion of ions inthesolution    

d) release of heat energy due toionization

Answer: b) free movement of ions in the solution

 

117.On passing electrical current through an electrolyte solution…………………

a) cations movetowardsanode     b) cations move towards cathode and anions towardsanode

c) anions movetowardscathode   d) both cations and anions move in samedirection

Answer: b) cations move towards cathode and anions towards anode

 

118.The fraction of total current carried by the cation and anion is termedas……………….

Answer: Transport number

 

119.The sum of the transport number of cation and anion is equalto…………….

a)1         b)0                   c)0.5                 d)Infinity

Answer: a) 1

 

120.The ionic mobility of Li+ is small as compared to that of K+. It is because Li+ ion is heavily hydrated (Say True orFalse)

Answer: True

 

121.One faraday is equalto………………..

a)96.500coulombs

b)9650coulombs 

c)965.00coupons

d)96500coulombs

Answer: d) 96500 coulombs

 

121. Corrosion isa(an)............... process.

a)oxidation     

b)reduction               

c)electrolysis   

d)erosi 

Answer: a) oxidation

 

122.………..metal is used as a coating on steel to limitcorrosion.

           Answer: Zinc

 

123.Corrosion startsat the …………. of the metal.

a) surface    b)middle      c)bottom           d)side

Answer: a) Surface

 

124.The electrode where reduction occursiscalled…………….

Answer: b) cathode

 

125.Positive electrode is known as……….

a)Terminal   b) Anode  c) Cathode d) None of these

Answer: b) Anode

 

126.Rust is………………….

a) Hydratedcoppersulphate        

b) Hydrated ferroussulphate

c) Hydratedferricoxide                 

D) Hydrated ferrousoxide.

Answer: c) Hydrated ferric oxide

 

127.Among lead, iron, chromium, and copper, the least easily oxidized metalis…………..

Answer: copper

 

128.Series connection of a number a number of cells is known as……………

Answer: battery.

 

129.Lead acid battery is a……………..battery.

a)Primary   

b) secondary  

c) quaternary  

d) None of these

Answer: b) secondary

 

130.The anode used in lead storage battery is……………

a)Pb         b)PbO2on Pb c)only PbO2d)Zn

Answer: a)Pb

 

131.In Daniel cell ………   are used as anode and cathode respectively.

a)Zn & Cu   b) Cu & Zn   c)Cu &Pb  d) Zn &Pb

Answer: a) Zn & Cu

 

132.In the electrolytic refining of metal,the pure metal is used as………..

Answer: cathode

 

133.In electrochemical cell electrical energy in converted in to chemical energy. (say true or false)

Answer: False

 

134.A beaker containing hot water, it is the example of ………..thermodynamic system.

Answer: open

 

135.The process in which the volume of the system is remains constant is called as ……….

a) Isobaricb) Isochoricc) Adiabatic   d) Isothermal

Answer: b) Isochoric

 

136.In endothermic process heat is _________.   

a)  Evolved   b) absorbed c) increased    d) decreased

Answer:b) absorbed

 

137.In exothermic process heat is _________.   

(a)  Evolved   (b) absorbed (c) increased    (d) decreased

Answer: a) evolved

 

138.The process in which the temperature of the system is remains constant is called asIsochoric.

(Say true or false)

Answer:False

 

139.The study of the flow of heat or any other form of energy into or out of a system undergoing

physicalor chemical change iscalled………………….

Answer: Thermodynamics

 

140.Thermodynamics is applicable to macroscopic systems only (Say True orFalse)

Answer: True

 

141.In an exothermic reaction the heat energy is……………..while in endothermic reaction itis…………

a)released,released         b) released, absorbed

c)absorbed,released       d) absorbed,absorbed

Answer: b) released, absorbed

 

142.The mathematical relation for the first law of thermodynamicsis……………

a)ΔE=q-w                                               b) ΔE=0 for acyclicprocess                   

c) ΔE=q for anisochoricprocess              d) all ofthese.

Answer: d) all of these

 

143.In an adiabatic process no heat can flow into or out of the system (Say True orFalse)

Answer: True

 

144.A thermoflask is an example of…………………

Answer: Isolated system

 

145.For an idealgas……………

Answer: PV = nRT

 

146.A process which proceeds of its own accord, without any outside assistance iscalled…………..

a) Non-spontaneousprocess        b) spontaneousprocess

c) Reversibleprocess                   d) irreversibleprocess

Answer: b) Spontaneous process

 

147.Entropy is ameasureof  of the molecules of thesystem.

a)Concentration   b)Velocity        c)zig-zagmotion             d) randomness ordisorder

Answer: d) randomness or disorder

 

148.A machine that can do work by using heat which flows out spontaneously from a high-temperature source to a low temperature sink iscalled…………………

a) Carnot machine    b) Cyclicmachine      c) Heatmachine              d) Heat engine

Answer: d) Heat engine

 

149.Mixing of two or more gases is a spontaneous process (Say True orFalse)

Answer: True

 

150.G is stands for……

Answer:  Change in Gibbs free energy.

 

151.H is stands for……

Answer:  Change in Enthalpy

 

152.S is stands for……

Answer:  Change in Entropy

 

153.The mathematical reaction for the first law of thermodynamics is…..

a) E=q-W                                           

b) E=0 for a cyclic process

c) E=q for an isochoric processes

d) all of these

Answer: d) all of these

 

154.A closed system is one which cannot transfer matter but transfer…………….to and from its surrounding.

a)Heat   b)work    c)radiation   d)all of these

Answer: d) all of these

 

155.Enthalpy is an example for………….. property.

a) Isothermal b) adiabatic   c) intensive d) extensive

Answer: d) extensive

 

156.An intensive property does not depend upon the………

a)Nature of the substance 

b) quantity of matter

c) External temperature      

d) atmospheric pressure

Answer: a) Nature of the substance

 

157.Precipitation of silver chloride from silver nitrate & sodium chloride is an example for………reaction

a)reversible b) irreversible c) neutral d) none of the above

Answer: b) irreversible

 

158.For an endothermic reaction………

a) (S > 0) & (+H)       

b) (S < 0) & (+H)        

c)(S< 0)&(-H)        

d) (S > 0)&(-H)

Answer:b) (S < 0) & (+H)

 

159.When……………., heat is transferred into the system.

a) q>0   b) q<0   c) q=0    d) all the above

Answer a)q>0

 

160.w<0 shows that, work is done ……the system.

a) on   b) by   c) through    d) all the above

Answer:  b) by

 

161………….is not an intensive property.

a)Volume  b)Pressure  c)Density   d)Concentration

Answer:  a) Volume

 

162.E is stands for……

Answer:  Change in Internal energy

 

163.The entropy of the system increases in the order…………………….

a) gas< liquid<solid    b) solid < liquid<gas   c) gas < solid<liquid          d) none ofthese

Answer: b) solid < liquid < gas

 

164.............. …… is the unit for entropy.

a)KJ mol-1                     b)JK-1mol          c)JK-1mol-1        d) KJmol

Answer: c)JK-1mol-1

 

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